基本资料

张国栋，河南商丘人。2012年6月在郑州大学获理学学士学位，同年通过推荐免试继续在郑州大学化学与分子工程学院攻读硕士，师从吴养洁院士。2015年9月受CSC资助,公派德国凯撒斯劳滕工业大学(Technische Universität Kaiserslautern) 攻读博士学位，导师 Lukas J. Gooßen教授。2016年9月随导师转学至波鸿鲁尔大学 (Ruhr-Universität Bochum), 并于2019年7月获理学博士学位。2019年12月入职扬州大学。

科研成果

22.    G. Zhang,* W. Tan, D. Zhang,*  K. Wang, P. Gao, S. Wang, S.-L. Liu,  F. Chen,*  Org. Lett. 2024, 26, 536−541: Regioselective Hydro(deutero)silylation of 1,3-Enynes Enabled by Photoredox/Nickel Dual Catalysis.

21.    G. Zhang,* K. Wang, D. Zhang,* C. Zhang, W. Tan, Z. Chen, F. Chen,*  Org. Lett. 2023, 25, 7406-7411: Decarboxylative Allylation of Silanecarboxylic Acids Enabled by Organophotocatalysis.

20.      G. Zhang,* C. Zhang, Y. Tian,  F. Chen,* Org. Lett. 2023, 25, 917−922: Fe-Catalyzed Direct Synthesis of Nitriles from Carboxylic Acids with Electron-Deficient N-Cyano-N-aryl–arylsulfonamide.

19.      G. Zhang,* C. Zhang, H. Jiao,*  F. Chen,* J. Catal. 2023, 418, 312-319: Photoredox/nickel cooperatively catalyzed radical allylic silylation of allyl acetates – Scope and mechanism.

18.    G. Zhang,* Y. Tian,  C. Zhang, X. Li,* F. Chen,* Chem. Commun. 2023, 59, 2449-2452: Decarboxylative C–H silylation of N-heteroarenes with silanecarboxylic acids.

17.       G. Zhang,* L.Wang, L. Cui, P. Gao,*  F. Chen,* Org. Biomol. Chem. 2023,21, 294-299: Deaminative defluoroalkylation of α-trifluoromethylalkenes enabled by photoredox catalysis.

16.      P. Gao,* L. Cui,   G. Zhang,* F. Chen,* Catal. Sci. Technol. 2023,13, 1628-1632: Visible-Light-Induced Decarboxylation/Defluorosilylation Protocol for Synthesis of gem-Difluoroalkenes.
15.     X. Li, Y. Shen, G. Zhang, X. Zheng, Q. Zhao, Z. Song, Org. Lett. 2022, 24, 5281–5286: Ru(II)-Catalyzed Decarbonylative Alkylation and Annulations of Benzaldehydes with Iodonium Ylides under Chelation Assistance.
14.       G. Zhang, Y. Cheng, M. Beller,* F. Chen,* Adv. Synth. Catal. 2021, 363, 1583–1596: Direct Carboxylation with Carbon Dioxide via Cooperative Photoredox and Transition-Metal Dual Catalysis.

13.       X.-Q. Hu,* Z.-K. Liu, Y.-X. Hou, G. Zhang,* Y. Gao.* Chem. Commun. 2021, 57, 1113−1116: Ru-catalysed C(sp2)–H vinylation/annulation of benzoic acids and alkynes: rapid access to medium-sized lactones.

12.  Z.  Hu, F. Belitz, G. Zhang, F. Papp,  L. J. Gooßen.* Org. Lett. 2021, 23, 3541−3545:Ru-Catalyzed (E)‑Specificortho-C−H Alkenylation of ArenecarboxylicAcids by Coupling with Alkenyl Bromides.

11.       Z. Hu, X.-Q. Hu, G. Zhang, L. J. Gooßen.* Org. Lett. 2019, 21, 6770−6773: Ring-Opening Ortho-C−H Allylation of Benzoic Acids with Vinylcyclopropanes: Merging Catalytic C−H and C−C Activation Concepts.

10.       G. Zhang, Z. Hu, G. Bertoli, L. J. Gooßen.* ACS Catal. 2019, 9, 8153−8158: Iridium-Catalyzed Synthesis of Substituted Indanones from Aromatic Carboxylates and Unsaturated Ketones. 

9.       G. Zhang, Z. Hu, F. Belitz, Y. Ou, N. Pirkl, L. J. Gooßen.* Angew. Chem. Int. Ed. 2019, 58, 6435−6439: Rh-Catalyzed Annelation of Benzoic Acids with α,β-Unsaturated Ketones with Cleavage of C−H, CO−OH, and C−C Bonds.

8.       G. Zhang, F. Jia, L. J. Gooßen.* Chem. Eur. J. 2018, 24, 4537–4541: Regioselective C−H Alkylation via Carboxylate‐Directed Hydroarylation in Water.

7.       X.-Q. Hu, Z. Hu, G. Zhang, N. Sivendran, L. J. Gooßen.* Org. Lett. 2018, 20, 4337−4340: Catalytic C–N and C–H Bond Activation: ortho-Allylation of Benzoic Acids with Allyl Amines.

6.       X.-Q. Hu, Z. Hu, A. S. Trita, G. Zhang, L. J. Gooßen.* Chem. Sci. 2018, 9, 5289–5294: Carboxylate-directed C–H allylation with allyl alcohols or ethers.

5.       L. Huang, A. Biafora, G. Zhang, V. Bragoni, L. J. Gooßen.* Angew. Chem. Int. Ed. 2016, 55, 6933–6937: Regioselective C−H Hydroarylation of Internal Alkynes with Arenecarboxylates: Carboxylates as Deciduous Directing Groups. 

4.   G. Zhang, S. Sun, F. Yang,* Q. Zhang, J. Kang, Y. Wu,* Y. Wu. * Adv. Synth. Catal. 2015, 357, 443–450: Arylmethyl Chlorides: New Bifunctional Reagents for Palladium-Catalyzed ortho-Chlorination and Acylation of 2-Arylpyridines. 

3.   G. Zhang, P. Wang, F. Yang,* Y. Wu.* Tetrahedron 2015, 71, 57–63: Copper-catalyzed synthesis of 2-arylbenzoxazoles from o-aminophenol derivatives with arylmethyl chlorides. 

2.   K. Xu, S. Sun, G. Zhang, F. Yang,* Y. Wu* RSC Adv. 2014, 4, 32643–32646: One-pot synthesis of unsymmetrical diarylacetylenes via Sonogashira/deacetonation/Sonogashira cross-coupling of two different aryl chlorides with 2-methyl-3-butyn-2-ol. 

1.   K. Xu, F. Yang,* G. Zhang, Y. Wu.* Green Chem. 2013, 15, 1055–1060: Palladacycle-catalyzed phosphonation of aryl halides in neat water. 

获奖情况                                                               

2015年河南省优秀硕士论文

2015年郑州大学优秀硕士论文

2019年第十届欧洲有机会议最佳Poster Presentation奖